Given below are two statements:
Statement I: Number of alpha hydrogens in 2,2,5,5-tetramethylhex-3-ene is zero.
Statement II: Trifluoroacetic acid is more acidic than Chloroacetic acid.
In the light of the above statements, choose the most appropriate answer from the options given below:
Text Solution
Verified by ExpertsC
• In 2,2,5,5-tetramethylhex-3-ene, the carbons
to the
(allylic carbons at C2 and C5) are quaternary
, so they bear no hydrogens
. (Allylic
carbon adjacent to
.)
•
is stronger than
because
exerts a much stronger
effect; the acidity order with
substituent highest (e.g.,
).
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